Report of the ACS Green Mountain Local Section
September 2005 Event
Dr. William H. Zoller
University of Washington
"Atmospheric Chemistry in
Hawai'i: The Long-Range Transport of Dust and Pollutants across the
Pacific Ocean”
Report By Martin Case:
There was certainly “something in the air” at Middlebury College last
month, when professor William Zoller from the University of Washington
captivated Green Mountain local section members and Middlebury students
alike with his lecture “Atmospheric Chemistry n Hawai’I: Long Range
Transport of Dust and Pollutants across the Pacific Ocean”. We were
left in no doubt about professor Zoller’s ground-breaking contributions
to the science of atmospheric sampling: from Hawai’i to Norway, and
high into the stratosphere prof. Zoller has been sampling aerosols from
volcanic and human activity for almost fifty years. Thanks to his work
we’ve learned much about acid rain, dust clouds, and how pollution
travels the globe impacting the most unlikely places. Perhaps
understandably, professor Zoller has chosen to focus his research on
Hawai’i. After all, this is one of the globe’s most active volcanic
regions and we learned much about the different make-up of gases from
“hot spots”, calderas and fumaroles. In contrast to the global
implications of his work, prof Zoller emphasized a meticulous attention
to detail in his sampling methods – a message that will hopefully be
taken back to the lab by the many Middlebury students in the audience.
The highlight of prof. Zoller’s talk was his defiant rebuttal of the
popular idea that a meteor impact off the coast of Mexico drove the
dinosaurs to extinction. Apparently, a careful examination of the KT
boundary layer reveals iridium levels typical of Earthly vulcanism in
the Deccan Traps of India rather than extraterrestrial visitors. Maybe
we can persuade Walter Alvarez to come and give us the other side of
the argument…?
Bills Bio:
Bill
Zoller grew up in Alaska during the 1950's and 60's. He graduated in
chemistry from the University of Alaska in 1965 and went to graduate
school at the Massachusetts Institute of Technology where he studied
nuclear chemistry and graduated in 1969 with a Ph.D. He became an
Assistant Professor of Chemistry at the University of Maryland in 1970
after a brief post doc at the University of Hawaii. He became a Full
Professor in 1969 at Maryland, and while there published numerous
research papers and led research programs in urban air pollution,
volcanic chemistry, and atmospheric chemistry in Antartica. He used
Instrumental Neutron Activation Analysis to measure trace elements in
samples from the atmosphere and to measure the release of radioisotopes
from atmospheric weapons testing and reactor accidents, such as
Chernobyl in the former Soviet Union.
Bills Abstract:
Atmospheric Aerosol samples were collect at the Mauna Loa
Meteorological Observatory on the Big Island of Hawaii from 1979-1992.
These filter samples were collected only during Down Slope winds
allowing one to sample to Free Troposphere with minimal Island
contamination. The filter samples were analyzed by Instrumental Neutron
Activation Analysis for approximately 35 trace elements. The source of
aerosols that were reaching the Observatory were the Queen (Na,Cl), and
continental dust (Al, Fe,Sc) from the surrounding continents, and Asian
dust which was one of the most dominate source for the Island. One
could also measure the quantity of Island weathering that contributed
to the aerosol loading. Pollutant transport from the surrounding
continents could occasionally be observed, and traced backed to the
source region using air mass trajectories. The combustion of Oil from
the Exxon Valdez in the Gulf of Alaska was also measured in Hawaii, as
the largest signal in the vanadium record over the entire collection
record.