CATL

CATALYSIS & SURFACE SCIENCE SECRETARIAT

L. S. Boff, Program Chair
N. B. Jackson, L. S. Boffa, Secretary General
OTHER SYMPOSIA OF INTEREST:
Asymmetric Reactions and Syntheses (see Division of Organic Chemistry, Sun, Mon, page xx)
Metal-Mediated Reactions, Physical Organic Chemistry, Photochemistry, and Materials (see Division of Organic Chemistry, Tue, page xx)
Molecular Engineering for Phase-Separable Catalysts (see Division of Inorganic Chemistry, Sun, Mon, Tue, page xx)
Synthesis and Characterization of Novel Micro/Meso Materials for Petrochemical Processing (see Division of Petroleum Chemistry, Wed, page xx)
Catalysis Award Symposium Honoring Alexis T. Bell (see Division of Colloid & Surface Chemistry, Sun, page xx)
Chemistry at Solid Surfaces (see Division of Colloid & Surface Chemistry, Mon, Tue, Wed, page xx)
New Polyolefin Copolymers: Synthesis, Properties, and Applications (see Division of Polymeric Materials: Science & Engineering, Sun, Mon, Tue, page xx)

SUNDAY MORNING

Wyndham Emerald Plaza
Pearl

Emission Control through Catalysis

Cosponsored with Division of Colloid & Surface Chemistry, Division of Industrial & Engineering Chemistry, and Division of Petroleum Chemistry

U. S. Ozkan, P. O'Connor, Organizers
U. S. Ozkan, Presiding

8:30—Introductory Remarks.

8:35—1. Improve FCC gasoline qualities and clean exhaust gases. C. Li, Z. Da, Z. He

8:55—2. FTIR study of the interaction of dioxin, carbazole, dibenzothiophene, and 4,6-dimethyldibenzothiophene on metal oxide catalysts. M. A. Larrubia, A. Gutierrez Alejandre, J. Ramirez Solis, G. Busca

9:15—3. Ultradeep HDS catalysis in production of clean diesel fuels. R. G. Leliveld, S. E. Eijsbouts, S. Mayo

9:35—4. New catalytic materials for hydrodesulfurization catalysis. M. E. Bussell, B. Diaz, D. C. Phillips, S. Korlann, R. L. Self, D. Shorten

9:55—Intermission.

10:20—5. Preparation of titania (TiO2) catalyst support of a large specific surface by applying the pH swing method for ultradeep HDS of diesel oil. S. Inoue, T. Takatsuka, H. Kudou, T. Ono, S. Nakata, Y. Yoshimura

10:40—6. Catalytic decarboxylation of low-rank Turkish Elbistan lignite. Y. Yürüm, S. Özvatan

11:00—7. NOx reductions under fluid catalytic cracking conditions. R. Roncolatto, L. Mello

11:20—8. Withdrawn.

SUNDAY AFTERNOON

Wyndham Emerald Plaza
Pearl

Emission Control through Catalysis

Cosponsored with Division of Colloid & Surface Chemistry, Division of Industrial & Engineering Chemistry, and Division of Petroleum Chemistry

U. S. Ozkan, P. O'Connor, Organizers
P. O'Connor, Presiding

1:30—9. Partial oxidation of methane to synthesis gas over alkaline earth metal oxide supported cobalt catalysts. H. Wang Sr., E. Ruckenstein Sr.

1:50—10. Influence of chromium on sulfur resistance of supported Pd catalyst for aromatic hydrogenation in diesel fuel. L. Hu, G. Xia, L. Qu, M. Li, D. Li

2:10—11. Production of hydrogen from the catalytic reformulation of methanol. P. H. Matter, S. Natesakhawat, U. S. Ozkan

2:30—12. Palladium-based catalysts for the synthesis of alcohols. M. J. Pérez-Zurita, M. L. Cubeiro, M. Cifarelli, M. Goldwasser, E. Pietri, L. V. García B, J. F. Lamonier

2:50—Intermission.

3:20—13. High-stability water-gas shift catalysts based on nanocrystalline ceria. Q. Fu, S. Kudriavtseva, H. Saltsburg, M. Flytzani-Stephanopoulos

3:40—14. First-principles modeling or reactions on oxide surfaces for automotive exhaust aftertreatment. W. F. Schneider, K. C. Hass, J. L. Gland, M. Miletic

4:00—15. Highly active lean NOx catalysts: Hysteresis in the presence of water. K. C. Ott, N. C. Clark, J. A. Rau

4:20—16. Withdrawn.

MONDAY MORNING

Wyndham Emerald Plaza
Pearl

Emission Control through Catalysis

Cosponsored with Division of Colloid & Surface Chemistry, Division of Industrial & Engineering Chemistry, and Division of Petroleum Chemistry

U. S. Ozkan, P. O'Connor, Organizers
P. O'Connor, Presiding

8:30—17. Characteristics of Cu/Ti-PILC catalyst for the reduction of NOx by propene. B. S. Kim, S-W. Ham, H-J. Chae, I-S. Nam

8:50—18. Identification of surface intermediates on palladium-based catalysts in NOx reduction with lower hydrocarbons. J. M. Watson, R. Munteanu, U. S. Ozkan

9:10—19. Low-temperature SCR of NO with NH3 over water-resistant transition-metal oxides supported on titania. B. S. Uphade, D. A. Peña, P. G. Smirniotis

9:30—20. Molecular beam study of NO reduction on rhodium catalysts. S. Wehner, C. S. Gopinath, F. Zaera

9:50—Intermission.

10:20—21. Spectroscopic and theoretical insight into the mechanistic aspects of SCR reaction over vanadia-titania catalysts. N-Y. Topsoe, M. Anstrom, J. A. Dumesic

10:40—22. Lean NOx catalysis for mobile source emission control. M. Crocker, S. Eckhoff, A. Fukumoto, T. Matsumoto, P. A. Duggleby, R. Bending

11:00—23. Poisoning effect of SO2 on NO reduction by i-butane over Fe/ZSM-5 prepared by sublimation method. S. I. Woo, P. Decyk, D-K. Kim, D. H. Kim, M. R. Kim

11:20—24. New active zeolite structures for the selective catalytic reduction of nitrogen oxides: ITQ-7 and IM5 zeolites—the influence of NO2 on this reaction. A. Corma, A. E. Palomares, J. G. Prato

MONDAY AFTERNOON

Wyndham Emerald Plaza
Pearl

Emission Control through Catalysis

Cosponsored with Division of Colloid & Surface Chemistry, Division of Industrial & Engineering Chemistry, and Division of Petroleum Chemistry

U. S. Ozkan, P. O'Connor, Organizers
U. S. Ozkan, Presiding

1:30—25. Study of the conversion of chlorided hydrocarbons over acid catalysts. E. Finocchio, C. Pistarino, G. Busca, M. Baldi

1:50—26. Unique materials design for catalytic emission control systems. P. O'Connor, D. Stamires, W. Jones

2:10—27. Development of an active and environmentally selective bifunctional metal-zeolite catalyst for the chlorinated VOC emissions abatement. A. Aranzabal, R. Lopez, J. R. Gonzalez-Velasco, J. I. Gutierrez-Ortiz, M. A. Gutierrez-Ortiz, J. A. Gonzalez-Marcos

2:30—28. Effect of particle size on oxidation processes on platinum catalysts. B. Trout, X. Lin, W. F. Schneider, K. C. Hass

2:50—Intermission.

3:20—29. Fluorine emission control of the semiconductor industry by surface wave plasma. B. Derecskei, M. Gunn, J. Bevan

3:40—30. Catalytic oxidation of Cl VOCs in flue gas from a waste incineration pilot plant. J. Corella, J-M. Toledo

4:00—31. Global warming potential reduction of the industrial SF6 emission by surface wave plasma. M. Gunn, B. Derecskei, J. Tomeo, J. Bevan

4:20—32. Thermoanalysis of three nuclear oxo-acetate cluster complexes of ferric(III) and chromium(III). S. K. Abdullaev, R. N. Nosirova, N. Q. Mukhamadiev

TUESDAY MORNING

Wyndham Emerald Plaza
Pearl

Nanotechnology in Catalysis

Nanomaterials for Advanced Catalysts

Cosponsored with Division of Colloid & Surface Chemistry and Division of Industrial & Engineering Chemistry

B. Zhou, J. St. John, Organizers
B. Zhou, Presiding

8:00—Introductory Remarks.

8:10—33. Fabrication of model platinum nanoparticle catalysts by electron-beam lithography: Studies of hydrogenation and dehydrogenation of cyclohexene. G. A. Somorjai

8:55—34. Nanostructure processing of advanced catalysts. J. Y. Ying

9:40—35. New catalytic materials for clean technology. K. Wilson, D. J. Macquarrie, J. H. Clark

10:05—36. Design of open metal sites in porous metal-organic crystals. O. M. Yaghi, B. Chen, M. O'Keeffe

10:30—37. Nanofunctionalization of catalysts for methanol-to-olefin chemistry. J. F. Haw, W. Song

10:55—38. Synthesis of nanocrystalline perovskites for catalytic combustion of methane. N. Sangar, J. Y. Ying

11:20—39. Nanocrystalline LaCoO3-based perovskites as catalysts for VOC oxidation. V. Szabo, M. Bassir, J. E. Gallot, A. V. N. Van Neste, S. Kaliaguine

11:45—40. Recent development in electron microscopy of nanoparticles and supported catalysts. J. Liu

TUESDAY AFTERNOON

Wyndham Emerald Plaza
Pearl

Nanotechnology in Catalysis

Ordered Nanoporous Materials for Catalysis

Cosponsored with Division of Colloid & Surface Chemistry and Division of Industrial & Engineering Chemistry

B. Zhou, J. St. John, Organizers
J. Y. Ying, Presiding

1:00—41. Mixed-metal clusters as precursors for nanoparticle bimetallic catalysts embedded in mesoporous silica MCM-41. S. Hermans, B. F. G. Johnson, R. Raja, G. Sankar, J. M. Thomas

1:25—42. Spontaneous formation of gold nanoparticles in MCM-41 mesoporous materials and their application in catalytic hydrogenation of styrene. P. Mukherjee, C. Patra, A. Ghosh, R. Kumar, M. Sastry

1:50—43. Transformations of ethylene sulfide on zeolites and a zeotype: The appearance of a seven-membered cyclic product with three-ring sulfur atoms on AlMCM-41, an aluminosilicate with nanosize pore system. I. Pálinkó, A. Fási, Á. Gömöry, I. Kiricsi

2:15—44. Size discrimination of colloidal nanoparticles by thiol-functionalized MCM-41 mesoporous molecular sieves. P. Mukherjee, M. Sastry, R. Kumar

2:40—45. Nanoparticles of 3-D transition-metal oxides in mesoporous MCM-48 silica host structures: Synthesis and characterization. R. Köhn, C. Minchev, M. Fröba

3:05—46. Ordered mesoporous carbons exhibiting extraordinary metal dispersion. R. Ryoo, S. H. Joo, S. J. Choi

3:30—47. Synthesis, characterization, and use of graphite nanofibers as novel support materials. P. E. Anderson, N. M. Rodriguez, T. K. Baker

3:55—48. Mesoporous silica thin films with various structures: In situ time-resolved XRD experiments. D. Grosso, F. Babonneau, P. A. Albouy, R. Balkenende, H. Amenitsch

4:20—49. One-pot synthesis of phenyl-functionalized porous silicates with hexagonal and cubic symmetries. V. Goletto, F. Babonneau, M. Impéror

4:45—50. Microwave-induced self-assembly of zeolite crystals. J. M. Kim, D. S. Kim, J. S. Hwang, J-S. Chang, S-E. Park

WEDNESDAY MORNING

Wyndham Emerald Plaza
Pearl

Nanotechnology in Catalysis

Catalysis by Nanoparticle/Nanoporous Materials

Cosponsored with Division of Colloid & Surface Chemistry and Division of Industrial & Engineering Chemistry

B. Zhou, J. St. John, Organizers
A. G. Comolli, Presiding

8:00—51. Catalysis by metallic nanoparticles: The good and the bad. M. A. El-Sayed

8:45—52. Nanoporous carbon membranes for catalysis and separation. H. C. Foley

9:30—53. Withdrawn.

9:30—54. Highly dispersed nitride supported on ã-alumina for hydrogenation of benzene and dehydrogenation of cyclohexane. J. Xiao, Z. Sun, Q. Xin, C. Li

9:55—55. Performance of nanonickel particles containing catalyst in the hydrogenation of toluene. L. H. Ding, Z. Zhang

10:20—56. Cooperative coadsorption of CO and O2 on gold clusters: Evidence for efficient room-temperature CO2 generation. W. T. Wallace, R. L. Whetten

10:45—57. Characterization and catalytic activity of gold nanoparticles synthesized by autoreduction of aqueous chloroaurate ions with fumed silica. P. Mukherjee, C. Patra, A. Ghosh, R. Kumar, M. Sastry

11:10—58. Selective molecular adsorption on gold clusters. R. L. Whetten, B. E. Salisbury, W. T. Wallace

WEDNESDAY AFTERNOON

Wyndham Emerald Plaza
Pearl

Nanotechnology in Catalysis

Catalysis and Characterization of Nanoparticle/Nanoporous Materials

Cosponsored with Division of Colloid & Surface Chemistry and Division of Industrial & Engineering Chemistry

B. Zhou, J. St. John, Organizers
J. St. John, Presiding

1:00—59. Size-dependent electrical behavior of spatially inhomogeneous barrier height regions on silicon. N. S. Lewis, R. C. Rossi, M. X. Tan

1:25—60. Tin/indium oxide nanocomposites for gas sensor applications. J. T. McCue, J. Y. Ying

1:50—61. Catalytic properties of mixed nanoparticles. M. B. Mitchell, V. N. Sheinker, A. B. Tesfamichael, A. A. Elliott, E. A. Mintz

2:15—62. Preparation and characterization of sulfated zirconia/silica super acid nanocatalyst. C. Wang, Y. Zhang, N. Gao, S. Lin, Y. Bai, Y. Wei

2:40—63. Highly selective dehydration of 4-methyl-2-pentanol to terminal olefin catalyzed by (hydrous) zirconia solid catalysts. S. Liu, G. K. Chuah

3:05—64. Synthesis of Ti-MWW as a catalyst for selective epoxidation of alkenes. T. Tatsumi, P. Wu

3:30—65. Construction of multisite chiral catalysts: Dendrimer-fixation of C2-symmetrical diphosphinerhodium complexes. G. D. Engel, L. H. Gade

3:55—66. High-resolution 23Na and 27Al solid-state NMR satellite transition spectroscopy. S. Shih, S. Ding, C. A. McDowell

4:20—67. Determination of thermodynamic parameters of nanoporous materials by frontal inverse gas chromatography. F. Thielmann, D. R. Williams

4:45—68. Application of solid-state multinuclear CPMAS (13C, 29Si, 119Sn) and CRAMPS (1H and 19F) NMR for the investigation of chiral transition-metal complexes supported on the surface of inorganic oxides modified with natural chiral polymers. Y. Oprunenko, D. Mityuk

THURSDAY MORNING

Wyndham Emerald Plaza
Pearl

Nanotechnology in Catalysis

New Concepts and Applications of Nanocatalysis

Cosponsored with Division of Colloid & Surface Chemistry and Division of Industrial & Engineering Chemistry

B. Zhou, J. St. John, Organizers
M. A. El-Sayed, Presiding

8:00—69. Design activity and selectivity in tailored nanoscale materials. J. Liu

8:45—70. First-principles simulations of catalysis and nanotechnology. W. A. Goddard, W. Deng, X. Xu, D. Chakraborty, D. Philipp

9:30—71. Amphoterization and layer-by-layer assembly of colloidal gold particles derivatized with the amino acid valine. P. Mukherjee, A. Kumar, A. B. Mandale, R. Kumar, M. Sastry

9:55—72. Autocatalytic formation of nanometer-sized metal particles during photographic development and in colloidal dispersions. G. Mills, K. Winkelmann, A. Korchev

10:20—73. EXAFS investigation of bimetallic materials for the synthesis of single-walled carbon nanotubes. T. Guo, G. Cheng, B. Lormand

10:45—74. Preparation and characterization of catalyst applied for synthesis of carbon nanotubes via CCVD method. Z. Konya, A. Oszko, A. Siska, J. Kiss, I. Kiricsi

11:10—75. Degradation of organic contaminants in drinking water and wastewater using a rotating disk photocatalytic reactor: Factors affecting interfacial transport, adsorption, and reaction. D. D. Dionysiou, M. T. Suidan, I. Baudin, J-M. Laîné

11:35—76. Simulation of the dynamic behavior of nanoparticle chain aggregates. A. Dalis, S. K. Friedlander